Lorentz JÄNTSCHI (lori) works ?id=171
- [id] => 171
- [recorddate] => 2008:10:21:19:56:59
- [lastupdate] => 2008:10:21:19:56:59
- [type] => article
- [place] => Sofia, Bulgaria
- [subject] => chemistry - general; informatics - applied; mathematics - applied; mathematics - modeling; mathematics - number theory
- [relatedworks] =>
- 4 (some):
- Statistical approach of structure-activity relationships: a case study, ?id=181

- [file] => ?f=171
- [mime] => application/pdf
- [size] => 154776
- [pubname] => International Journal of Pure and Applied Mathematics
- [pubinfo] => Academic Publications
- [pubkey] => ISSN 1311-8080
- [workinfo] => 47(1): 9-16, Zbl pre05492616
- [year] => 2008
- [title] => Model formulation & interpretation - from experiment to theory
- [authors] => Carmen E. STOENOIU, Sorana D. BOLBOACĂ, Lorentz JÄNTSCHI
- [abstract] =>

From kinetics study of a given pair of reactants different types of mechanisms were investigated. A mathematical model was formulated. Model parameters were evaluated and assessed. Obtained results from the optimization procedure opened an interesting discussion about the limits of experiments parameters for imposed conditions, such as mechanism type and collecting procedure.

By using of a least squares method were obtained models as best fits correlates (results shown an average of 96.6%) with experimental measurements. Comparison between experiments shown that the obtained model is a consistent one, all obtained parameters being in the same range of 95% confidence interval. These results validates experimental as well as from model data.
- [keywords] => Mathematical modeling, Reaction mechanism, Model assessment